NickelMaghrebV1, France, Analysis, bibRecord, 000141

New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[M"(H20)6](S04)2.4H2O (M": Co, Ni) : Structure, reactivity and thermal decomposition

Identifieur interne : 000141 ( France/Analysis ); précédent : 000140; suivant : 000142

New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[M"(H20)6](S04)2.4H2O (M": Co, Ni) : Structure, reactivity and thermal decomposition

Auteurs : Walid Rekik [Tunisie] ; Houcine Naïli [Tunisie] ; Tahar Mhiri [Tunisie] ; Thierry Bataille [France]

Source :

Solid state sciences [ 1293-2558 ] ; 2009.

RBID : Pascal:09-0181805

Descripteurs français

Pascal (Inist)
- Composé de métal de transition, Sulfate, Réaction dirigée, Décomposition thermique, Matériau hybride, Méthode évaporation lente, Réseau monoclinique, Structure cristalline, Groupe espace, Paramètre cristallin, Structure supramoléculaire, Liaison hydrogène, Déshydratation, Nickel, Humidité, Précurseur, Thermogravimétrie, Dépendance température, Diffraction RX, Hydrate, Composé anhydre, Amine, 8120K, 6166H.
Wicri :
- topic : Déshydratation, Nickel.

English descriptors

KwdEn :
- Amines, Anhydrous compound, Crystal structure, Dehydration, Humidity, Hybrid material, Hydrates, Hydrogen bonds, Lattice parameters, Monoclinic lattices, Nickel, Precursor, Slow evaporation method, Space groups, Sulfates, Supramolecular structure, Temperature dependence, Template reaction, Thermal decomposition, Thermogravimetry, Transition element compounds, XRD.

Abstract

Two new hybrid materials, (C₄H₁₄N₂)[M¹¹(H₂O)₆](SO₄)₂.4H₂O (M^II: Co (I), Ni (II)), have been synthesised by slow evaporation method at room temperature and crystallographically characterized. They crystallise isotypically in the monoclinic system, space group F2₁/n, with the following unit-cell parameters a=9.2285(3), b=11.3333(4), c = 10.6693(4) A, β=109.004(2)°, Z=2 and V=1055.07(6) Å³ for I and a=9.2127(2), b=11.3182(2), c=10.6434(2)Å, β=109.094(1)°, Z=2 and V=1048.74(4)Å³ for II. The structure of the two supramolecular compounds consists of metallic cation octahedrally coordinated to six water molecules, sulfate anions, 1,4-butanediammonium cation and water molecules linked together via two types of hydrogen bonds, O-H...O and N-H...O. The two compounds are not stable at room temperature and their partial dehydration depends on the humidity of the environment. The thermal decomposition of precursors, studied by thermogravimetric analysis (TG) and temperature-dependent X-ray diffraction (TDXD), shows successive intermediate hydrates and crystalline anhydrous compounds upon dehydration.

Affiliations:

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Pascal:09-0181805

Le document en format XML

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H<sub>14</sub>
N<sub>2</sub>
)[M"(H<sub>2</sub>
0)<sub>6</sub>
](S0<sub>4</sub>
)<sub>2</sub>
.4H<sub>2</sub>
O (M": Co, Ni) : Structure, reactivity and thermal decomposition</title>
<author><name sortKey="Rekik, Walid" sort="Rekik, Walid" uniqKey="Rekik W" first="Walid" last="Rekik">Walid Rekik</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">New transition metal sulfates templated by 1,4-butanediamine, (C<sub>4</sub>
H<sub>14</sub>
N<sub>2</sub>
)[M"(H<sub>2</sub>
0)<sub>6</sub>
](S0<sub>4</sub>
)<sub>2</sub>
.4H<sub>2</sub>
O (M": Co, Ni) : Structure, reactivity and thermal decomposition</title>
<author><name sortKey="Rekik, Walid" sort="Rekik, Walid" uniqKey="Rekik W" first="Walid" last="Rekik">Walid Rekik</name>
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<sZ>1 aut.</sZ>
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<author><name sortKey="Naili, Houcine" sort="Naili, Houcine" uniqKey="Naili H" first="Houcine" last="Naïli">Houcine Naïli</name>
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</author>
<author><name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire de l'Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, BP 802</s1>
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<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Tunisie</country>
<wicri:noRegion>3018 Sfax</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Bataille, Thierry" sort="Bataille, Thierry" uniqKey="Bataille T" first="Thierry" last="Bataille">Thierry Bataille</name>
<affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Sciences Chimiques de Rennes (CNRS, UMR 6226), Université de Rennes 1, Avenue du Général Leclerc</s1>
<s2>35042 Rennes</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Région Bretagne</region>
<settlement type="city">Rennes</settlement>
</placeName>
<orgName type="university">Université de Rennes 1</orgName>
</affiliation>
</author>
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<series><title level="j" type="main">Solid state sciences</title>
<title level="j" type="abbreviated">Solid state sci.</title>
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<imprint><date when="2009">2009</date>
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<seriesStmt><title level="j" type="main">Solid state sciences</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Amines</term>
<term>Anhydrous compound</term>
<term>Crystal structure</term>
<term>Dehydration</term>
<term>Humidity</term>
<term>Hybrid material</term>
<term>Hydrates</term>
<term>Hydrogen bonds</term>
<term>Lattice parameters</term>
<term>Monoclinic lattices</term>
<term>Nickel</term>
<term>Precursor</term>
<term>Slow evaporation method</term>
<term>Space groups</term>
<term>Sulfates</term>
<term>Supramolecular structure</term>
<term>Temperature dependence</term>
<term>Template reaction</term>
<term>Thermal decomposition</term>
<term>Thermogravimetry</term>
<term>Transition element compounds</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Composé de métal de transition</term>
<term>Sulfate</term>
<term>Réaction dirigée</term>
<term>Décomposition thermique</term>
<term>Matériau hybride</term>
<term>Méthode évaporation lente</term>
<term>Réseau monoclinique</term>
<term>Structure cristalline</term>
<term>Groupe espace</term>
<term>Paramètre cristallin</term>
<term>Structure supramoléculaire</term>
<term>Liaison hydrogène</term>
<term>Déshydratation</term>
<term>Nickel</term>
<term>Humidité</term>
<term>Précurseur</term>
<term>Thermogravimétrie</term>
<term>Dépendance température</term>
<term>Diffraction RX</term>
<term>Hydrate</term>
<term>Composé anhydre</term>
<term>Amine</term>
<term>8120K</term>
<term>6166H</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Déshydratation</term>
<term>Nickel</term>
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<front><div type="abstract" xml:lang="en">Two new hybrid materials, (C<sub>4</sub>
H<sub>14</sub>
N<sub>2</sub>
)[M<sup>11</sup>
(H<sub>2</sub>
O)<sub>6</sub>
](SO<sub>4</sub>
)<sub>2</sub>
.4H<sub>2</sub>
O (M<sup>II</sup>
: Co (I), Ni (II)), have been synthesised by slow evaporation method at room temperature and crystallographically characterized. They crystallise isotypically in the monoclinic system, space group F2<sub>1</sub>
/n, with the following unit-cell parameters a=9.2285(3), b=11.3333(4), c = 10.6693(4) A, β=109.004(2)°, Z=2 and V=1055.07(6) Å<sup>3</sup>
 for I and a=9.2127(2), b=11.3182(2), c=10.6434(2)Å, β=109.094(1)°, Z=2 and V=1048.74(4)Å<sup>3</sup>
 for II. The structure of the two supramolecular compounds consists of metallic cation octahedrally coordinated to six water molecules, sulfate anions, 1,4-butanediammonium cation and water molecules linked together via two types of hydrogen bonds, O-H...O and N-H...O. The two compounds are not stable at room temperature and their partial dehydration depends on the humidity of the environment. The thermal decomposition of precursors, studied by thermogravimetric analysis (TG) and temperature-dependent X-ray diffraction (TDXD), shows successive intermediate hydrates and crystalline anhydrous compounds upon dehydration.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Tunisie</li>
</country>
<region><li>Région Bretagne</li>
</region>
<settlement><li>Rennes</li>
</settlement>
<orgName><li>Université de Rennes 1</li>
</orgName>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Rekik, Walid" sort="Rekik, Walid" uniqKey="Rekik W" first="Walid" last="Rekik">Walid Rekik</name>
</noRegion>
<name sortKey="Mhiri, Tahar" sort="Mhiri, Tahar" uniqKey="Mhiri T" first="Tahar" last="Mhiri">Tahar Mhiri</name>
<name sortKey="Naili, Houcine" sort="Naili, Houcine" uniqKey="Naili H" first="Houcine" last="Naïli">Houcine Naïli</name>
</country>
<country name="France"><region name="Région Bretagne"><name sortKey="Bataille, Thierry" sort="Bataille, Thierry" uniqKey="Bataille T" first="Thierry" last="Bataille">Thierry Bataille</name>
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</record>

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New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[M"(H20)6](S04)2.4H2O (M": Co, Ni) : Structure, reactivity and thermal decomposition

New transition metal sulfates templated by 1,4-butanediamine, (C4H14N2)[M"(H20)6](S04)2.4H2O (M": Co, Ni) : Structure, reactivity and thermal decomposition

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri